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The longest word is pneumonoultramicroscopicsiliciavolcanoconiosis. This is a 43 letter word. Other long words include:
Intercomprehensivenesses (22 letters)
Semiautobiographical (20 letters)
Pseudopseudohypoparathyroidism (30 letters)
In Finland there is sentence that is almost impossible to say: Kokoo koko kokko kokoon. Koko kokkoko kokoon? Koko kokko kokoon. Which means: Build whole bonfire together. Whole bonfire together? Whole bonfire.